Check out SoftwareFor.org: Free Software for You. From their web site,
The Software for Starving Students CD enhances the Windows and Mac desktop computing experiences by providing an easy way to install free, high-quality software titles via a user-friendly interface. It includes popular open source programs like Firefox and OpenOffice, intended to help students learn about and benefit from open source and free software programs. The SSS team put all the most commonly used free programs onto one CD to make it easier for students to install useful software (including fully-featured office suites, 3D graphic editors and much more) for free.